Iridium(III) acetylacetonate CAS NO.15635-87-7
| Name | Iridium(III) acetylacetonate | ||
| CAS NO. | 15635-87-7 | ||
| Molecular Formula | C15H21IrO6 | Molecular Weight | 489.54 |
| MDL No. | N.A. | EINECS | 239-711-8 |
| M.P. | 269-271 °C(lit.) | B.P. | 260°C/1mmHg |
| Density | N.A. | Refractive Index | N.A. |
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F.P. |
N.A. | Storage condition | under inert gas (nitrogen or Argon) at 2-8°C |
| Appearance | orange-yellow crystal | ||
| Purity | |||
| Application | Iridium acetylacetonate (Ir(acac)3) has a low sublimation temperature, good volatility, and film-forming properties. In the early 1980s, Harding did pioneering work using iridium acetylacetonate as a precursor to make high-purity Ir coatings. (1) Using Ir(acac)3 as a precursor and MOCVD technology to prepare Ir coatings, it has been widely used as a base material for engines in missiles, rockets, cruisers, and cars. (2) Using Ir(acac)3 as a deposition source to prepare Ir-C cluster films on ZrO2 substrates, which have excellent electrochemical properties. (3) Ir(acac)3 is used as a catalyst for the hydrogenation of sulfur-containing aromatics. (4) Ir(acac)3 is a strong photoreducing agent in phenylpyridine aqueous solutions. (5) By using commercial carbon black as the carbon source, 2-methylimidazole and iridium acetylacetonate as the nitrogen and iridium sources, atomically dispersed Ir-N-C catalysts were successfully prepared. | ||
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